Electrochemistry MCQs 2026
48 questions with detailed answers · 17 from past papers · 5 quiz batches available
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- Q1 Past Paper · PPSC/FPSC/NTS medium
The oxidation state of chlorine in NaCl is
💡 Explanation:Chlorine, being more electronegative, takes on a -1 oxidation state in sodium chloride.
- Q2 easy
In a galvanic cell, electrons flow through the external circuit from the
💡 Explanation:Electrons released at the anode travel through the external wire to the cathode.
- Q3 Past Paper · PPSC/FPSC/NTS easy
The function of a salt bridge in a galvanic cell is to
💡 Explanation:The salt bridge completes the circuit and keeps both half-cells electrically neutral as ions migrate.
- Q4 easy
In an electrolytic cell, electrical energy is used to
💡 Explanation:Electrolytic cells use an external power source to force a non-spontaneous reaction to occur.
- Q5 medium
In an electrolytic cell, the anode is connected to the ___ terminal of the external battery
💡 Explanation:In electrolysis, the anode is connected to the positive terminal of the external power source.
- Q6 Past Paper · PPSC/FPSC/NTS medium
The oxidation number of oxygen in most compounds is
💡 Explanation:Oxygen typically has an oxidation state of -2 in most of its compounds.
- Q7 medium
The oxidation number of hydrogen in most compounds is
💡 Explanation:Hydrogen typically has an oxidation state of +1, except in metal hydrides.
- Q8 Past Paper · PPSC/FPSC/NTS medium
The oxidation number of a free element (uncombined) is always
💡 Explanation:Atoms in their elemental, uncombined form always have an oxidation number of zero.
- Q9 medium
Electrolysis of molten sodium chloride produces
💡 Explanation:Molten NaCl electrolysis deposits sodium metal at the cathode and releases chlorine gas at the anode.
- Q10 medium
Electroplating uses the principle of
💡 Explanation:Electroplating passes current through an electrolyte to deposit a thin metal layer on an object.
- Q11 Past Paper · PPSC/FPSC/NTS medium
The standard hydrogen electrode (SHE) is assigned a standard reduction potential of
💡 Explanation:The SHE is the universal reference electrode, defined as having exactly 0.00 V potential.
- Q12 medium
A metal with a more positive standard reduction potential than hydrogen will
💡 Explanation:Metals less reactive than hydrogen (higher reduction potential) cannot displace it from dilute acids.
- Q13 medium
According to the electrochemical (activity) series, the most reactive metal listed is generally
💡 Explanation:Potassium sits near the top of the activity series as one of the most reactive metals.
- Q14 Past Paper · PPSC/FPSC/NTS medium
According to the electrochemical series, the least reactive metal (most easily reduced) is generally
💡 Explanation:Gold is placed at the bottom of the activity series, being highly resistant to oxidation.
- Q15 medium
A spontaneous redox reaction has a standard cell potential (E°cell) that is
💡 Explanation:A positive E°cell value indicates the reaction is thermodynamically spontaneous.
- Q16 medium
The relationship between Gibbs free energy and cell potential is given by
💡 Explanation:The equation ΔG° = −nFE° links a cell's spontaneity directly to its free energy change.
- Q17 Past Paper · PPSC/FPSC/NTS medium
In a Daniell cell, the two electrodes used are
💡 Explanation:The classic Daniell cell uses a zinc anode and a copper cathode.
- Q18 medium
In a lead-acid battery (car battery), the electrolyte used is
💡 Explanation:Lead-acid batteries use dilute sulfuric acid as their electrolyte.
- Q19 medium
A dry cell (common battery) uses ___ as its electrolyte
💡 Explanation:Dry cells use a moist paste of ammonium chloride or zinc chloride as the electrolyte.
- Q20 Past Paper · PPSC/FPSC/NTS medium
Corrosion of iron (rusting) is fundamentally an example of
💡 Explanation:Rusting involves the oxidation of iron and reduction of oxygen, an electrochemical process.
- Q21 medium
Galvanization protects iron from rusting by coating it with a layer of
💡 Explanation:Galvanization coats iron with a sacrificial layer of zinc to prevent rusting.
- Q22 medium
Which of the following metals would displace copper from copper sulfate solution
💡 Explanation:Zinc is more reactive than copper, allowing it to displace copper from its salt solution.
- Q23 medium
Faraday's first law of electrolysis states that the mass of a substance deposited at an electrode is directly proportional to the
💡 Explanation:Faraday's first law relates deposited mass directly to the total charge passed.
- Q24 Past Paper · PPSC/FPSC/NTS medium
Faraday's second law of electrolysis relates the mass of substances deposited by the same quantity of charge to their
💡 Explanation:Faraday's second law states that for a given charge, deposited masses are proportional to equivalent weights.
- Q25 medium
The unit of electric charge used in Faraday's laws, one Faraday, is approximately equal to the charge on
💡 Explanation:One Faraday equals the total charge carried by one mole of electrons, about 96,500 coulombs.
- Q26 medium
A fuel cell generates electricity through the electrochemical reaction of
💡 Explanation:Hydrogen fuel cells generate electricity by combining hydrogen and oxygen, producing water as byproduct.
- Q27 Past Paper · PPSC/FPSC/NTS medium
Which of the following is a secondary (rechargeable) cell
💡 Explanation:Lead-acid batteries can be recharged by reversing the current, making them secondary cells.
- Q28 medium
A primary cell is one that
💡 Explanation:Primary cells are single-use, as their chemical reactants cannot be regenerated by recharging.
- Q29 medium
In an electrolytic cell used for electrorefining of copper, the impure copper is used as the
💡 Explanation:Impure copper is made the anode so it dissolves into solution during electrorefining.
- Q30 Past Paper · PPSC/FPSC/NTS medium
During electrorefining of copper, pure copper is deposited at the
💡 Explanation:Copper ions from solution are reduced and deposited as pure copper at the cathode.
- Q31 medium
The SI unit of electrode potential is the
💡 Explanation:Electrode potential, a measure of electrical potential difference, is expressed in volts.
- Q32 hard
The number of electrons transferred when Fe2+ is oxidized to Fe3+ is
💡 Explanation:Fe2+ loses exactly one electron to become Fe3+.
- Q33 hard
In the reactivity series, metals above hydrogen can generally
💡 Explanation:Metals more reactive than hydrogen can displace it from dilute acids, releasing hydrogen gas.
- Q34 hard
Which of the following best defines an electrolyte
💡 Explanation:Electrolytes conduct electric current through the movement of ions when molten or dissolved.
- Q35 Past Paper · PPSC/FPSC/NTS hard
Which of the following processes occurs at the cathode in any electrochemical cell (galvanic or electrolytic)
💡 Explanation:By definition, reduction always occurs at the cathode in both galvanic and electrolytic cells.
- Q36 hard
The standard electrode potential of a half-cell is measured relative to the
💡 Explanation:All standard electrode potentials are conventionally measured against the standard hydrogen electrode.
- Q37 hard
A cell in which the overall reaction produces electrical energy from a spontaneous chemical reaction is called a
💡 Explanation:Galvanic cells convert the energy of a spontaneous redox reaction directly into electrical energy.
- Q38 Past Paper · PPSC/FPSC/NTS hard
In the electrolysis of aqueous sodium chloride (brine), the gas produced at the anode is
💡 Explanation:Chloride ions are oxidized at the anode during brine electrolysis, releasing chlorine gas.
- Q39 hard
In the electrolysis of aqueous sodium chloride (brine), the gas produced at the cathode is
💡 Explanation:Water is reduced at the cathode during brine electrolysis, releasing hydrogen gas.
- Q40 hard
A concentration cell generates electric current due to a difference in the
💡 Explanation:Concentration cells use identical electrodes but different electrolyte concentrations to generate a potential difference.
- Q41 Past Paper · PPSC/FPSC/NTS hard
Anodizing is an electrolytic process most commonly used to increase the thickness of the natural oxide layer on
💡 Explanation:Anodizing is widely applied to aluminum to build a thicker, more protective oxide coating.
- Q42 medium
The process of purifying an impure metal using electrolysis is called
💡 Explanation:Electrorefining uses electrolysis to purify an impure metal, depositing pure metal at the cathode.
- Q43 easy
Oxidation is defined as the process involving
💡 Explanation:Oxidation is defined as the loss of one or more electrons by a substance.
- Q44 Past Paper · PPSC/FPSC/NTS easy
Reduction is defined as the process involving
💡 Explanation:Reduction involves gaining one or more electrons.
- Q45 Past Paper · PPSC/FPSC/NTS easy
A redox reaction always involves
💡 Explanation:Electrons lost in oxidation must be gained somewhere, so oxidation and reduction always occur together.
- Q46 easy
The substance that gets oxidized in a redox reaction and causes reduction of another substance is called the
💡 Explanation:The reducing agent donates electrons, itself becoming oxidized, while reducing another species.
- Q47 Past Paper · PPSC/FPSC/NTS easy
The substance that gets reduced and causes oxidation of another substance is called the
💡 Explanation:The oxidizing agent accepts electrons, itself becoming reduced, while oxidizing another species.
- Q48 easy
In an electrochemical (galvanic/voltaic) cell, oxidation occurs at the
💡 Explanation:By convention, oxidation always takes place at the anode of an electrochemical cell.